全文获取类型
收费全文 | 690篇 |
免费 | 182篇 |
国内免费 | 35篇 |
专业分类
化学 | 126篇 |
晶体学 | 24篇 |
力学 | 43篇 |
综合类 | 2篇 |
数学 | 306篇 |
物理学 | 406篇 |
出版年
2024年 | 1篇 |
2023年 | 19篇 |
2022年 | 33篇 |
2021年 | 50篇 |
2020年 | 40篇 |
2019年 | 33篇 |
2018年 | 28篇 |
2017年 | 47篇 |
2016年 | 47篇 |
2015年 | 49篇 |
2014年 | 69篇 |
2013年 | 63篇 |
2012年 | 77篇 |
2011年 | 67篇 |
2010年 | 60篇 |
2009年 | 62篇 |
2008年 | 29篇 |
2007年 | 36篇 |
2006年 | 22篇 |
2005年 | 12篇 |
2004年 | 13篇 |
2003年 | 13篇 |
2002年 | 5篇 |
2001年 | 13篇 |
2000年 | 5篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 2篇 |
排序方式: 共有907条查询结果,搜索用时 15 毫秒
31.
32.
《中国化学快报》2020,31(6):1540-1544
Although platinum-based materials are regarded as the state-of-the-art electro-catalysts for hydrogen evolution reaction(HER),high cost and quantity scarcity hamper their scale-up utilization in industrial deployment.Herein,a one-step strategy was developed to synthesize multi-walled carbon nanotubes and reduced graphene oxide supported Pt nanoparticle hydrogel(PtNP/rGO-MWCNT),in which only ascorbic acid was used as the reductant for one-pot reduction of both GO and chloroplatinic acid.The hydrogel can be directly used as a flexible binder-free catalytic electrode to achieve high performance of HER.Compared to conventional strategies,the current strategy not only significantly reduces the Pt loading to 3.48 wt%,simplifies the synthesis process,but also eliminates the use of any polymer binders,thus decreasing the series resistance and improving catalytic activity.An overpotential of only 11 mV was achieved on as-prepared PtNP/rGO-MWCNT to drive a geometrical current density of 10 mA/cm2 in0.5 mol/L H2 SO4,with its catalytic activity being kept over 15 h.In acidic medium,the HER activity of the PtNP/rGO-MWCNT catalyst exceeds most of the reported Pt-based electro-catalysts and is 3-fold higher than that obtained on commercial Pt/C electrode. 相似文献
33.
A chaotic model of spontaneous (without external stimulus) neuron firing has been analyzed by mapping the irregular spiking time-series into telegraph signals. In this model the fundamental frequency of chaotic Rössler attractor provides (with a period doubling) the strong periodic component of the generated irregular signal. The exponentially decaying broad-band part of the spectrum of the Rössler attractor has been transformed by the threshold firing mechanism into a scaling tale. These results are compared with irregular spiking time-series obtained in vitro from a spontaneous activity of hippocampal (CA3) singular neurons (rat’s brain slice culture). The comparison shows good agreement between the model and experimentally obtained spectra. 相似文献
34.
In this paper we study the problems of centers and isochronous centers and the local bifurcation of critical periods for a Liénard system with forth damping. Calculating the singular point values and period constants, we find all center conditions and isochronous center conditions. Moreover, the numbers of local critical periods bifurcating from centers and isochronous centers is obtained by computing the orders of weak centers. 相似文献
35.
Solving diffusion equation using wavelet method 总被引:1,自引:0,他引:1
Xuefeng ChenJiawei Xiang 《Applied mathematics and computation》2011,217(13):6426-6432
A wavelet-based numerical method based on wavelets of Hermite cubic splines is presented for computing singularly perturbed convection-dominated diffusion equation. The advantages of the method are explained. To improve the accuracy of singular areas, wavelets are configured hierarchically for solving algebraic equations. Numerical examples show that the proposed method has good efficiency and precision. 相似文献
36.
《Communications in Nonlinear Science & Numerical Simulation》2011,16(6):2397-2404
The minimum entropy (ME) control is a chaos control technique which causes chaotic behavior to vanish by stabilizing unstable periodic orbits of the system without using mathematical model of the system. In this technique some controller type, normally delayed feedback controller, with an adjustable parameter such as feedback gain is used. The adjustable parameter is determined such that the entropy of the system is minimized. Proposed in this paper is the PSO-based multi-variable ME control. In this technique two or more control parameters are adjusted concurrently either in a single or in multiple control inputs. Thus it is possible to use two or more feedback terms in the delayed feedback controller and adjust their gains. Also the multi-variable ME control can be used in multi-input systems. The minimizing engine in this technique is the particle swarm optimizer. Using online PSO, the PSO-based multi-variable ME control technique is applied to stabilize the 1-cycle fixed points of the Logistic map, the Hénon map, and the chaotic Duffing system. The results exhibit good effectiveness and performance of this controller. 相似文献
37.
白花败酱矿物质元素分析与利用 总被引:1,自引:0,他引:1
罗梅兰 《广东微量元素科学》2014,(7):25-27
目的对野生白花败酱与栽培白花败酱8种矿物质元素进行了测定、分析与利用。方法采用火焰原子吸收分光光度法。结果白花败酱的嫩茎叶含有丰富的K、Ca、Na、Mg常量元素和Fe、Mn、Cu、Zn微量元素,栽培种的Mn含量是野生种的4倍多。结论白花败酱可作蔬菜食用,同时对土壤中的Mn有富集能力。 相似文献
38.
Peng Lv Zhong-min Wang Nian-lei Shi Huai-ying Zhou Jian-qiu Deng Qing-rong Yao Huai-gang Zhang 《Russian Journal of Electrochemistry》2014,50(10):953-958
A series of experiments were performed to investigate the effect of TiMn1.5 alloying on the structure, hydrogen storage properties and electrochemical properties of LaNi3.8Co1.1Mn0.1 hydrogen storage alloys at 303 K. For simple, A, B, and C are used to represent alloys (x = 0 wt %, x = 4 wt % and x = 8 wt %) respectively. The results of XRD and SEM show that LaNi3.8Co1.1Mn0.1?xTiMn1.5 hydrogen storage alloys have LaNi5 phase and (NiCo)3Ti phase. Based on the results of PCT curves, the hydrogen storage capacities of LaNi3.8Co1.1Mn0.1?xTiMn1.5 hydrogen storage alloys are about 1.28 wt % (A), 1.16 wt % (B) and 1.01 wt % (C) at 303 K. And the released pressure platform and the pressure hysteresis decrease with the increase of TiMn1.5 content. Meanwhile the activation curves show that LaNi3.8Co1.1Mn0.1?xTiMn1.5 hydrogen storage alloy electrodes can be activated in three times and the maximum discharge capacity is 343.74 mA h/g at 303 K. In addition, with the increase of TiMn1.5 content, the cyclic stability of the hydrogen storage alloy electrodes decreases obviously and the capacity retention decreases from 76.70% to 70.00% when TiMn1.5 content increases from A to C. It also can be seen that LaNi3.8Co1.1Mn0.1?xTiMn1.5 hydrogen storage alloy electrode C and B have the best self-discharge ability and the best high-rate discharge ability from self-discharge curves and high-rate discharge curves. 相似文献
39.
THE CONSTRUCTION OF WAVELET-BASED TRUNCATED CONICAL SHELL ELEMENT USING B-SPLINE WAVELET ON THE INTERVAL 总被引:4,自引:0,他引:4
Xiang Jiawei He Zhengjia Chen Xuefeng 《Acta Mechanica Solida Sinica》2006,19(4):316-326
Based on B-spline wavelet on the interval (BSWI), two classes of truncated conicalshell elements were constructed to solve axisymmetric problems, i.e. BSWI thin truncated conicalshell element and BSWI moderately thick truncated conical shell element with independent slope-deformation interpolation. In the construction of wavelet-based element, instead of traditionalpolynomial interpolation, the scaling functions of BSWI were employed to form the shape functionsthrough the constructed elemental transformation matrix,and then construct BSWI element viathe variational principle. Unlike the process of direct wavelets adding in the wavelet Galerkinmethod, the elemental displacement field represented by the coefficients of wavelets expansionwas transformed into edges and internal modes via the constructed transformation matrix. BSWIelement combines the accuracy of B-spline function approximation and various wavelet-basedelements for structural analysis. Some static and dynamic numerical examples of conical shellswere studied to demonstrate the present element with higher efficiency and precision than thetraditional element. 相似文献
40.
Electroluminescence enhancement in ultraviolet organic light‐emitting diode with graded hole‐injection and ‐transporting structure 下载免费PDF全文
Xiaowen Zhang Bingjie Mo Fengjiao You Xiujuan Zhou Liming Liu Honghang Wang Bin Wei 《固体物理学:研究快报》2015,9(6):353-357
Electroluminescent intensity and external quantum efficiency (EQE) in ultraviolet organic light‐emitting diodes (UV OLEDs) have been remarkably enhanced by using a graded hole‐injection and ‐transporting (HIT) structure of MoO3/N,N ′‐bis(naphthalen‐1‐yl)‐N,N ′‐bis(phenyl)‐benzidine/MoO3/4,4′‐bis(carbazol‐9‐yl)biphenyl (CBP). The graded‐HIT based UV OLED shows superior short‐wavelength emis‐ sion with spectral peak of ~410 nm, maximum electroluminescent intensity of 2.2 mW/cm2 at 215 mA/cm2 and an EQE of 0.72% at 5.5 mA/cm2. Impedance spectroscopy is employed to clarify the enhanced hole‐injection and ‐transporting capacity of the graded‐HIT structure. Our results provide a simple and effective approach for constructing efficient UV OLEDs. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献